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Synthesis 2021; 53(19): 3535-3544
DOI: 10.1055/a-1493-6670
DOI: 10.1055/a-1493-6670
feature
Aza-Peterson Olefinations: Rapid Synthesis of (E)-Alkenes
We thank Manchester Metropolitan University (MMU) for startup funding. T.K.B. thanks MMU for Strategic Opportunities Funding. M.G.M. thanks MMU, Royal Society of Chemistry and Medical Research Council for funding.
Abstract
An aza-Peterson olefination methodology to access 1,3-dienes and stilbene derivatives from the corresponding allyl- or benzyltrimethylsilane is described. Silanes can be deprotonated using Schlosser’s base and added to N-phenyl imines or ketones to directly give the desired products in high yields.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-1493-6670.
- Supporting Information
Publikationsverlauf
Eingereicht: 31. März 2021
Angenommen nach Revision: 28. April 2021
Accepted Manuscript online:
28. April 2021
Artikel online veröffentlicht:
25. Mai 2021
© 2021. Thieme. All rights reserved
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