Synthesis, Inhaltsverzeichnis Synthesis 2021; 53(13): 2240-2252DOI: 10.1055/a-1384-1967 paper Diastereoselective trans Cyclopropanation of 3-Alkylidene Oxindoles with In Situ Generated α-Diazo Carbonyls or α,β-Unsaturated Diazo Compounds Authors Institutsangaben Sayan Pramanik a Department of Chemistry, University of Calcutta, 92 APC Road, Kolkata 700009, India Suman Ray b Department of Chemistry, Presidency University, Kolkata 700073, India Suvendu Maity c Department of Chemistry, R. K. Mission Residential College, Narendrapur, Kolkata 700103, India Prasanta Ghosh c Department of Chemistry, R. K. Mission Residential College, Narendrapur, Kolkata 700103, India Chhanda Mukhopadhyay ∗ a Department of Chemistry, University of Calcutta, 92 APC Road, Kolkata 700009, India Artikel empfehlen Abstract Artikel einzeln kaufen(opens in new window) Alle Artikel dieser Rubrik(opens in new window) Abstract An efficient diastereoselective trans cyclopropanation of 3-alkylidene oxindoles with in situ generated α-diazo carbonyl compounds or α,β-unsaturated diazo compounds under metal-free conditions has been developed to synthesize 3-spirocyclopropyl-2-oxindole derivatives. The procedure is based on the 1,3-dipolar character of the corresponding diazo compounds under base-catalyzed conditions. The method has a wide substrate scope and uses easily available starting materials. Key words Key wordsdiastereoselectivity - trans cyclopropanation - diazo compounds - 1,3-dipoles - spiro compounds - oxindoles Volltext Referenzen References 1a Nicolaou KC, Vourloumis D, Winssinger N, Baran PS. Angew. 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