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Yoshikai, N. : 2023 Science of Synthesis, 2023/3: Base-Metal Catalysis 2 DOI: 10.1055/sos-SD-239-00318
Base-Metal Catalysis 2

2.12 Asymmetric C—H Oxidation with Biologically Inspired Manganese and Iron Catalysts

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Editor: Yoshikai, N. 

Authors: Adak, L. ; Aoki, S.; Banerjee, S. ; Bedford, R. B. ; Cheng, Z.; Costas, M. ; Gao, M.; Garai, B.; Ge, S. ; Gosmini, C. ; Hota, S. K.; Ilies, L. ; Jindal, A.; Kawanaka, Y.; Li, H. ; Li, M.; Liu, Q. ; Lu, Z. ; Mandal, R.; Matsunaga, S. ; Murarka, S. ; Nakamura, M. ; Nolla-Saltiel, R. ; Ollevier, T. ; Palone, A. ; Panda, S. P.; Sahoo, S.; Sang, J.; Schiltz, P.; Shenvi, R. A. ; Sundararaju, B. ; van der Puyl, V. ; Vicens, L. ; Wang, C. ; Wang, Y. ; Yang, X.; Yang, Y.; Yoshikai, N. ; Yoshino, T. ; Zeng, X. ; Zhang, G. 

Title: Base-Metal Catalysis 2

Print ISBN: 9783132455030; Online ISBN: 9783132455054; Book DOI: 10.1055/b000000440

1st edition © 2023 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

Enantioselective oxidation of aliphatic C—H bonds is the most straightforward and atom-economical approach to prepare chiral oxygenated hydrocarbon skeletons, which are ubiquitous in molecules of biological and industrial relevance. In Nature, this reaction is carried out by metalloenzymes with high levels of efficiency and selectivity. Due to the exquisite performance of enzymatic systems, their active site has served as inspiration for the exploration of artificial catalysts, such as those based on porphyrins or coordination compounds with tetradentate salen- or bis-amine-bis-pyridine-type ligands. Reviewed herein are the latest advances in enantioselective C—H oxidations using biologically inspired iron and manganese complexes.

Key words

iron catalysis - manganese catalysis - C–H functionalization - oxidation - asymmetric synthesis - bioinspired complexes - catalyst design - porphyrins - salen ligands - enantioselectivity
 
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