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Fernández, E.: 2020 Science of Synthesis, 2019/6: Advances in Organoboron Chemistry towards Organic Synthesis DOI: 10.1055/sos-SD-230-00042
Advances in Organoboron Chemistry towards Organic Synthesis

4 Synthesis of gem-Diboron Compounds from Diboron Reagents

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Book

Editor: Fernández, E.

Authors: Aggarwal, V. K.; Ahmed, E.-A. M. A.; Aiken, S. G.; Bateman, J. M.; Boldrini, C.; Bose, S. K.; Carbó, J. J.; Cho, H. Y.; Clark, T. B.; Fernández, E.; Fu, Y.; Geetharani, K.; Gong, T.-J.; Ito, H.; Kitanosono, T.; Kobayashi, S.; Kubota, K.; Maseras, F.; Ohmiya, H.; Pineschi, M.; Ping, Y.; Sawamura, M.; Wang, J.; Wang, Y.-F.; Wu, C.; Xu, L.; Yoshida, H.; Zhang, F.-L.

Title: Advances in Organoboron Chemistry towards Organic Synthesis

Print ISBN: 9783132429710; Online ISBN: 9783132429758; Book DOI: 10.1055/b-006-164898

1st edition © 2020. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Kobayashi, S.; Koch, G.; Molander, G. A.; Nevado, C.; Trost, B. M.; You, S.-L.

Type: Multivolume Edition

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Abstract

gem-Diboron compounds are important intermediates in organic synthesis. In recent decades, a variety of methods for the preparation of gem-diboron compounds have been developed, among which, insertion into B–B bonds represents a unique approach. This chapter summarizes the synthesis of gem-diboron compounds based on insertion reactions into diboron compounds. These reactions include the diborylation of gem-dibromides, alkenes, benzylic C–H bonds, carbonyls, carbamates, and diazo compounds.

Key words

gem-diboron compounds - borylation - diborylation - alkenes - carbonyl compounds - carbamates - hydrazones - diazo compounds - gem-dibromides - transition-metal catalysis
 
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