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de Vries, J. G.: 2018 Science of Synthesis, 2017/5: Catalytic Reduction in Organic Synthesis 1 DOI: 10.1055/sos-SD-226-00114
Catalytic Reduction in Organic Synthesis 1

1.9 Hydrogenation of Carbon Dioxide

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Editor: de Vries, J. G.

Authors: Bonrath, W.; Cazin, C. ; Chen, Z.-P.; Dai, X.; de Vries, J. G.; Ding, K. ; Ghosh, B.; Hudson, R.; Kaneda, K. ; Li, Y.; Lv, H. ; Maleczka, Jr., R.; Medlock, J.; Mitsudome, T.; Moores, A.; Müller, M.-A.; Nahra, F. ; Nakagawa, Y.; Poechlauer, P.; Ravasio, N.; Shi, F.; Tamura, M.; Tan, X.; Tin, S.; Tomishige, K.; Zaccheria, F.; Zhang, X.; Zhou, Y.-G. ; Zimmermann, A.

Title: Catalytic Reduction in Organic Synthesis 1

Print ISBN: 9783132406216; Online ISBN: 9783132406254; Book DOI: 10.1055/b-005-145236

1st edition © 2018. Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Reference Libraries



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Fürstner, A. (Editor-in-Chief); Carreira, E. M.; Faul, M.; Koch, G.; Molander, G. A.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

Carbon dioxide is an economical, safe, and renewable C1 source. This attractive C1 building block is mainly used in the synthesis of organic chemicals, materials, and carbohydrates. As a feedstock to produce chemicals and fuel derivatives, carbon dioxide utilization will most certainly become an important tool in the quest for more sustainable chemistry. The atom-economical hydrogenation of carbon dioxide using dihydrogen offers a unique opportunity to achieve that goal. The main products of carbon dioxide hydrogenation or reduction fall into two categories: fuels and chemicals. The main topics discussed in this chapter are the hydrogenation of carbon dioxide to formic acid, methanol, and methane, as well as the reductive methylation of amines and C—H bonds. Both homogeneous and heterogeneous catalytic metal systems are reviewed herein.

Key words

carbon dioxide - formic acid - formates - methanol - hydrogenation - homogeneous catalysis - heterogeneous catalysis - reductive methylation - reduction
 
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