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Cazin, C.  et al.: 2018 Science of Synthesis, 2016/5b: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 2 DOI: 10.1055/sos-SD-224-00184
N-Heterocyclic Carbenes in Catalytic Organic Synthesis 2

2.7.2 Covalently Immobilized N-Heterocyclic Carbene Complexes

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Book

Editors: Cazin, C. ; Nolan, S.

Authors: Basle, O.; Broggi, J.; Claver, C.; Clavier, H.; Collins, S. K.; Costabile, C.; Crevisy, C.; Crozet, D.; Davies, A.; Diesendruck, C. E.; Felten, S.; Godard, C.; Grela, K.; Holtz-Mulholland, M.; Jana, A.; Johnson, J.; Lapkin, A.; Liu, J.; Lombardía, A.; Louie, J.; Malecki, P.; Mauduit, M.; Munz, D.; Nelson, D.; Peñafiel, I.; Schmid, T.; Slugovc, C.; Smith, A. D.; Thieuleux, C.; Zhong, Y.

Title: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 2

Print ISBN: 9783132414006; Online ISBN: 9783132414044; Book DOI: 10.1055/b-004-140260

1st edition © 2018 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

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Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

This chapter focuses on the preparation and the catalytic performance of metal–NHC complexes immobilized on oxide supports, which are designed so that the metal–NHC complex is maintained on the support during catalysis. The major scientific contributions for the covalent immobilization of metal–NHC complexes onto various oxides are covered, with an emphasis on the most distinguished examples. Particular attention is directed toward the anchoring of metal complexes via the substituents or the backbone of the NHC ligand, or via another X/L-type ligand that is not expected to suffer from decoordination during the catalytic process.

Key words

N-heterocyclic carbene complexes - supported catalysts - grafting - immobilization - oxides - sol-gel process - catalysis
 
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