2.1. 4 Enyne Metathesis
Book
Editors: Cazin, C. ; Nolan, S.
Title: N-Heterocyclic Carbenes in Catalytic Organic Synthesis 2
Print ISBN: 9783132414006; Online ISBN: 9783132414044; Book DOI: 10.1055/b-004-140260
1st edition © 2018 Georg Thieme Verlag KG
Georg Thieme Verlag, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Reference Libraries
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Koch, G.; Molander, G.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Type: Multivolume Edition
Abstract
Enyne metathesis is a metal-catalyzed reaction between an alkene and an alkyne, resulting in C–C bond formation to give a 1,3-diene. This chapter explores the different forms of this powerful reaction, both as a single reaction and as part of a reaction cascade to form polycyclic compounds.
Key words
metathesis - carbon–carbon bond formation - enynes - dienes - cyclization - polycyclic compounds - cascade reactions - metallacycles - N-heterocyclic carbenes- 1 Diver ST, Griffiths JR, In Olefin Metathesis: Theory and Practice. Grela K, Ed.;. Wiley Hoboken, NJ 2014); p ; 153
- 4 N-Heterocyclic Carbenes: Effective Tools for Organometallic Synthesis. Nolan SP, Ed.;. Wiley-VCH; Weinheim, Germany 2014
- 20 Żukowska K, Grela K, In Comprehensive Organic Synthesis II. Knochel P, Molander GA, Eds.;. Elsevier; Amsterdam 2014);. Vol. 5, p 1257.