39.32. 2.2 Alkanetellurolates of Group 3–12 Metals (Update 2014)
Book
Editors: Banert, K.; Brøndsted Nielsen, M.; Drabowicz, J.; Joule, J. A.; Schaumann, E.; Weinreb, S. M.
Title: Knowledge Updates 2014/3
Print ISBN: 9783131762818; Online ISBN: 9783131975119; Book DOI: 10.1055/b-003-125830
1st edition © 2014 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart
Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry
Science of Synthesis Knowledge Updates
Parent publication
Title: Science of Synthesis
DOI: 10.1055/b-00000101
Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.
Type: Multivolume Edition
Abstract
This chapter is an update to the earlier Science of Synthesis contribution (Section 39.32.2) describing methods for the synthesis of transition metal alkanetellurolates and their applications in organic synthesis. Synthetic methods developed in recent years concern both terminal and bridging alkanetellurolates. New applications for this class of compounds in organic synthesis have not been proposed. However, they have been postulated as catalytic intermediates in some transition-metal-mediated cross-coupling reactions.
Key words
transition metals - bridged compounds - tellurium compounds - tellurides - oxidative addition - cross-coupling reactions- 5 Shieh M, Ho L.-F, Chen P.-C, Hsu M.-H, Chen H.-L, Guo Y.-W, Pan Y.-W, Lin Y.-C. Organometallics 2007; 26: 6184