39.19.2.3 Alkaneselenolates of Group 3–12 Metals (Update 2014)

Abstract

This chapter is an update to the earlier Science of Synthesis contribution (Section 39.19.2) describing methods for the synthesis of transition metal selenolates and their applications in organic synthesis. Synthetic methods developed in recent years concern both terminal and bridging alkaneselenolates. New applications for this class of compounds in organic synthesis have not been proposed. However, compounds of this class have been postulated as catalytic intermediates in some reactions, such as transition-metal-catalyzed Se-C bond formation via cross-coupling reactions.

Schlüsselwörter

transition metals - bridged compounds - selenium compounds - selenides - selenols - oxidative addition - cross-coupling reactions

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