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Banert, K. et al.: 2014 Science of Synthesis, 2014/3: Knowledge Updates 2014/3 DOI: 10.1055/sos-SD-124-00136
Knowledge Updates 2014/3

24.2.1.3 1,1-Dihaloalk-1-enes (Update 2014)

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Book

Editors: Banert, K.; Brøndsted Nielsen, M.; Drabowicz, J.; Joule, J. A.; Schaumann, E.; Weinreb, S. M.

Authors: Aitken, R. A.; Ameduri, B.; Braverman, S.; Brøndsted Nielsen, M.; Cherkinsky, M.; Heydt, H.; Meehan, A.; Petersen, A. U.; Polo, A.; Real, J.; Stanforth, S. P.; Udmark, J.

Title: Knowledge Updates 2014/3

Print ISBN: 9783131762818; Online ISBN: 9783131975119; Book DOI: 10.1055/b-003-125830

1st edition © 2014 Thieme. All rights reserved.
Georg Thieme Verlag KG, Stuttgart

Subjects: Organic Chemistry;Chemical Reactions, Catalysis;Organometallic Chemistry;Laboratory Techniques, Stoichiometry

Science of Synthesis Knowledge Updates



Parent publication

Title: Science of Synthesis

DOI: 10.1055/b-00000101

Series Editors: Carreira, E. M.; Decicco, C. P.; Fürstner, A.; Molander, G. A.; Schaumann, E.; Shibasaki, M.; Thomas, E. J.; Trost, B. M.

Type: Multivolume Edition

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Abstract

This chapter is an update to the earlier Science of Synthesis contribution describing methods and strategies for the synthesis of 1,1-dihaloalk-1-enes. This update focuses on the preparation and polymerization of 1,1-difluoroalk-1-enes, including trifluorovinyl functional monomers. Radical additions of chain-transfer agents onto commercially available fluoroalkenes are described, followed by their chemical modification to yield original fluorinated monomers. These monomers are further involved in radical (conventional or controlled) copolymerizations with vinylidene fluoride (1,1-difluoroethene) or chlorotrifluoroethene to achieve high-value-added materials.

Key words

1,1-dihaloalk-1-enes - chlorotrifluoroethene - fluoropolymers - fuel-cell membranes - NMR - radical copolymerization - trifluorovinyl functional monomers - vinylidene fluoride - 1,1-difluoroethene
 
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