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Synfacts 2007(8): 0814-0814  
DOI: 10.1055/s-2007-968778
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag Stuttgart · New York

Tetracene Sulfoxides and Sulfones via a Cascade Cyclization

Contributor(s): Timothy M. Swager, Eric L. Dane
Y.-C. Lin, C.-H. Lin*
Academia Sinica, Nankang, Taiwan
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Publikationsverlauf

Publikationsdatum:
24. Juli 2007 (online)

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Significance

The authors report an unconventional synthesis of tetracene derivatives through the cyclization of ortho-diallene intermediates. They also report a one-pot synthesis of tetracene sulfoxide 3 (R1 = R2 = H) from the dialdehyde and lithium phenyl acetylide in 22% yield.