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Synfacts 2007(2): 0195-0195
DOI: 10.1055/s-2006-955805
DOI: 10.1055/s-2006-955805
Metal-Mediated Synthesis
© Georg Thieme Verlag Stuttgart · New York
A Versatile Triol Ligand for Cu-Catalyzed Reactions of Aryl Iodides
Y.-J. Chen*, H.-H. Chen
National Chung-Hsing University, Taiwan
Further Information
Publication History
Publication Date:
23 January 2007 (online)
Significance
Reactions of aryl halides with heteroatomic nucleophiles have become an important method for the preparation of numerous intermediates in organic synthesis. This publication describes a new simple and versatile protocol for the copper-catalyzed arylation of amides, phenols and thiols with aryl iodides in the presence of a simple triol ligand. The reaction conditions are mild and the reaction may tolerate various functional groups.